From Pc World:
The Disc Rot Myth
Media obsolescence isn't the only thing people fear after committing a personal library's worth of data to CDs and DVDs. But some worries--namely, fear of disc rot--are not fully warranted.
Like a bad seed, the myth of disc rot self-perpetuates, cropping up every now and again as a sudden and mortal threat to your copious collection of prerecorded and self-created discs.
The myth was once rooted in fact. It is true that back in the 1980s, with the first generation of prerecorded audio CDs, the edges of the discs were not always sealed properly, which allowed moisture to get into the disc. Replicated, prerecorded discs use aluminum for the reflective layer; when moisture came into contact with the aluminum on prerecorded discs, explains Byers, it in turn oxidized, causing the aluminum to become dull. "That's where the term 'rot' started," he says.
But that problem was quickly identified and overcome. "The manufacturers learned what was going on, so now the edges of discs are sealed with a lacquer," according to Byers. Though the problem is typically associated with CDs, Byers notes that the potential for interaction with oxygen is the same with both CD-ROMs and DVD-ROMs.
The so-called rot issue does not apply to recordable discs. For one thing, recordable optical media do not use aluminum; instead, they use silver, and very rarely gold, or a silver-gold alloy, for the reflective layer. "If the silver comes into contact with sulfates [i.e., pollution, or high humidity], it could affect the silver, but the likelihood of that is less than the likelihood of moisture coming into contact with the aluminum on prerecorded discs," says Byers.
Enduring Myth
The term rot has persisted, however inaccurately, as a means of identifying a plethora of problems with optical discs. "If you get a faulty disc and see a problem that you can visually see, you call it rot, but it could be the way the disc was manufactured," says Byers. "Or if it was subjected to extreme moisture and that moisture came into contact with the aluminum, it could be that the reflectivity has changed. It's not really rot, it's oxidation of aluminum. It should be a rare event on a disc, unless it's defective."
Beyond the realm of defective discs, improper handling can cause otherwise good discs to go bad. Since there's little protection between the label side of a CD and the data layer itself, "scratches on the label side can scratch the metal, and that will ruin the data," says Byers. It's not an issue for DVDs, though, since the dye layer is sandwiched between two plastic layers.
Byers observed a similar problem occurring with press-on labels: "For long-term storage, we recommend not using press-on labels on CDs; when these start to dry up, they can peel the metal right up, damaging data."
